Name: 010-000-054 R-(+)-1.1-Binaphthyl-2.2-diphemyl phosphine
SKU: 010-000-054

SKU: 010-000-054 Categories: Catalysts and Ligands, Industrial & Lab Chemicals

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CAS: 76189-55-4
MF: C₄₄H₃₂P₂
MW: 622.67
Assay: 0.98

Description

Water Solubility: Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.

Sensitive: Air Sensitive
R-(+)-1.1-Binaphthyl-2.2-diphemyl phosphine Chemical Properties 1.1′-Binaphthyl-2.2′-diphemyl phosphine is White to light beige powder R-(+)-1.1-Binaphthyl-2.2-diphemyl phosphine Uses It is an essential role in the organic synthesis of enantioselective transformations catalyzed by the complexes of ruthenium, rhodium and palladium. It is also employed in palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines. used with Cu(II) to catalyze the addition of arylsulfonamides to styrenes and olefins. R-(+)-1.1-Binaphthyl-2.2-diphemyl phosphine Reactions Phosphine Ligand Kit component. Useful ligand for palladium-catalyzed carbon-nitrogen bond formation. Useful ligand for rhodium-catalyzed C-C bond formation. Useful ligand for palladium-catalyzed intramolecular acylation of aryl bromides via C-H activation. Used in the preparation of Buchwald third generation precatalyst. Used in methoxy directed Rhodium migration. Used in Nickel catalyzed C-N cross-coupling reactions.

010-000-054 R-(+)-1.1-Binaphthyl-2.2-diphemyl phosphine

Description