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010-000-050 Diphenylphosphine

SKU: 010-000-050 Categories: ,
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CAS: 829-85-6
MF: C12H11P
MW: 186.19
Assay: 98%

Description

Description

Diphenylphosphine Synonyms

PH2PH;HPPh2;98% Ph2PH;AURORA KA-1107;Diphenylphosphin;DIPHENYLPHOSPHINE;Diphenyl phospine;Diphenyl-phosphane;PHOSPHINE, DIPHENYL;DPP/DIPHENYLPHOSPHIN

Diphenylphosphine Properties

Melting point: -14.5 °C
Boiling point: 280 °C(lit.)
Density: 1.07 g/mL at 25 °C(lit.)
Vapor pressure: 2 mm Hg ( 110 °C)
Refractive index : n20/D 1.625(lit.)
Flash point: -18°C (Hexane)
Storage temp. : 2-8°C
Form: liquid
Color: colorless
Specific Gravity: 0.68
Water Solubility: Miscible with ethanol, ether, benzene, concentrated hydrochloric acid. Immiscible with water.
Sensitive: Air & Moisture Sensitive

Diphenylphosphine Application

Diphenylphosphine acts as an intermediate in the preparation of diphenylphosphide derivatives, phosphonium salts, phosphine ligands, and Wittig-Horner reagents. The presence of hydrogen atom bonded to phosphorus undergoes Michael-like addition to activated alkenes. It is involved in the preparation of 1,2-bis(diphenylphosphino)ethane and (phenyl-(phenylmethyl)phosphoryl)benzene. Further, it is used in the synthesis of aminophosphines and chiral palladacycles with N-heterocyclic carbene ligands as catalysts.

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